Proceedings of the Third Internatiional Symposium m on Renewable E Energy and Sustaainability, Temixco, Moreloos, México, Septeember 9-11, 20155 EELECTROCHEMICAL GR ROWTH OF P POLY‐(3,4‐EETHYLENEDIIOXYTHIOPH HENE) ( (E‐PEDOT) A AND MANIP PULATION O OF ITS COND DUCTIVE STTATE FOR USE AS ANODIC BUFFER R LAYER IN O ORGANIC P PHOTOVOLTTAIC CELLS J. A. Del‐Oso1,2*, B. A. Frontana‐Uribe2, J. L. Maldon nado3, R. Mend doza1, M. Riveera‐ 4 Heernández 1 Universidad Autóónoma de la Ciuudad de Méxicoo, Prolongación SSan Isidro No. 151, San Lorenzoo Tezonco, 2 Ixttapalapa, 09790, México D.F., Mééxico. Centro Conjunto de Invesstigación en Quím mica Sustentable UAEMéx‐ 3 UN NAM, Carretera Toluca‐Atlacomul T n Cayetano‐Tolucca, Estado de Mééxico, México. Centro de lco Km 14.5, San 4 Invvestigaciones en Óptica A.P. 1‐9448, 37000 León, Gto., México. Instituto de Fíísica, Universidad d Nacional Au utónoma de M México, Apdo. P Postal 20‐364, 01000, México D.F., México. *Correspondingg author: alffredo.deloso@uacm.edu.mx Th his contribu ution presen nts the man nipulation o of morpholo ogy, thickneess and co onductancee of the polyymer film po oly[ethyleneedioxythiop phene] (PED DOT) by ellectrochemical growth h (CV or CA A) (E‐PEDOT), from th he monomeer 3,4‐ 1 etthylenedioxxythiophenee (EDOT), deposited o onto indium m‐tin oxidee (ITO). Fo or this studyy, different mixtures off anhydrouss organic so olvents weree used, reesulting in slow polym merization kinetics k of the monom mer EDOT2 when to oluene‐acettonitrile (4:1 1, v/v) wass used. Also o, was deteermined in which m monomer co oncentration n and electtropolymeriization poteential, allow wed us to o obtain beetter contro ol the growtth of the polymer to be b used as buffer 3 laayer of Orgganic Photo ovoltaic Cellls (OPVs). Furthermo ore, the prrevious co onditions w where corrrelated witth the film m conductaance of E‐PEDOT obtained and d transpareency in thee region UV V‐Vis. Finallyy, these E‐PEDOT used in OPV Vs togetherr with bulkk heterojuncction archittecture films were u nd their peerformance was comp pared with those consstructed wiith the an classical spin coating deposited PED DOT:PSS layeers. J. A. Del‐Oso, B.. A. Frontana‐U Uribe, J. L. Maldonado, R. Meendoza, M. Rivvera‐Hernándezz (2015) on of its Eleectrochemical growth of poly‐(3,4‐ethyleneedioxythiophene) (e‐pedot) and manipulatio co onductive state for use as ano odic buffer layeer in organic ph hotovoltaic cellls. Poster Session: Solar En nergy; Proceediings of the Thirrd Internationall Symposium on n Renewable En nergy and Susta ainability Proceedings of the Third Internatiional Symposium m on Renewable E Energy and Sustaainability, Temixco, Moreloos, México, Septeember 9-11, 20155 (Eds. E. Santoyo,, P.J. Sebastian n, M. López de Haro), Temixcco, Morelos, M México, Septemb ber 9‐11, 20015.