c c c c c c c c HYSYS 3.2 Bases de la Simulación ASPEN TECH TERMODINAMICA DEL HYSYS 2 cc ccc c cc c c ccc c c c c c c c c c c c c c c cccc cc c ccc c ccc c c c cc c cc c c c c cccc c c cc c c !ccc c c c c cc cccc cc c c c ccc cc c c c c c c c c "c c c c c c c c c c c #$c c c c c c c c c %c c c c c c c c c c c c c c c ccc&cc c cc c c c c c c c c c c c c c "c c c c c c c c c cc c c cc cc cccc c c %c" cc cccc c c c ccc c cc cc cc c cc c cc c cc c c c c c c c cc '())c c c c c '*)))c c cccc c "+cccc c cccc cc ccc cccc c c c c c c c c"c c c c c c c c & c c c c c c c c c c c c c c c c c c " c c c c c c c "cc# cc c c ccc c& "cc c cc%c cc"c & c c c" c c cc c cc c c c c c c %c c c c c c c c c c c c & c c c c c c c c cc cc c 2cc c c c c c" c c c ccc ccc c c c c c c c c c c c c c c c c c c c " c c , c c c c c c c cc& c c cc%c c cc c c-./0c c c c c c c c c c c " c c -./1-c .&c /3c c /c c %c c -./0c c c c c c c c c c c c c & c c cc% c c + c c c c c c c c c c c c c c c c cc cc c %c c c c c " c c c c c c c c c c c c c c c c c c c c c cc-./0c ccc c cccccc c c cc cc " c c cc c cccc c" cc-./0c Administrador de la Base de Simulación (Simulation Basis Manager) sccccc ccc cc cc cc c c c c c c %c # c c c 4 c c c 1Simulation Basis Manager3c c c c " c c c c c c c c c c c c c c c c & c c c c s c c c c c c c c c 1Build Environment3c c c c c c c c c ccccc c cc cc5 cc c c c c c& ccc cc c c c c ccc cccc " cc &c c c c" c & cccc c cc cc c" cc c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c cc cc c" 6c c þc c c c c c c c c c c c c c c c c þc ccccc cccc2 cc7 c þc c c c c c c c c c c c %c c c c c c c c c c c c c c c c c c c 4/c 1Simulation Basis Manager3c c c c c c c c c - c c c c c c c c c c c c c c 4/c c c c c c 4/c c cc c " c cc " cc cc c c c ccc c ccc cccccc4/cc c cc+c c c c c c c c c c c c cc " c c c cc c c ccc c" c cc& "cc ccccc2 cc c c cc c " cc c c c " c c c c c 4/c c c c cc - c c cc c c c c c c c c c &c c c c " c c c c c c 14 c %3c c%c &c c " c6c c Do you wish to be Left in HOLDING mode when entering the interactive Simulation Environment? c cc2 cc2 c1Property Pkg3cc# cc c4 cc cSBMccc cc c2 cc7 cc c c - cc cc c c! c cc4/cc cc c" ccc c c cccc c cc c c c c c c c" cc c" ccc c cc4/6c c Pagina Descripción 2c c c c c c -c c c Components c c c 2 c c 7 c c - c c " c c c ccccc cc c cc c c c c c c-cc % c c c c c c c "c c c c c cc cc 2c c c c c c c c c Fluid Pkgs c c c c c c #c c c " c c c c c c c c c c " c c " c c c c c c c c c c c c c c c c c c c c c c c c " c c 2c c c c c c c Hypothétical " c c c c c c c ccc cc c 2c c ccc# cc- c1Oil Oil Manager Manager3c c c c c c " c c c c c c c c c c c c c c c c cc c2 cc7 c 2c c c c c c c c Reactions c c cc cc c c c2 cc 7 c 2c c cc c cc c c Component Maps c c2 cc7 c - cc c cc c ccc cc User Property & c ccc c2 cc7 c ccc c c c c c c c c c c c c c c c c c c c Vc Componentes V.Vc Introducción %c cc-c1Components Manager3cc c c c c " c Components c 4/c c %c # c c -c c c c c c c c c & "c c c c c c c c c %c & "c c c c " c &c c c c c c c -c c c c c c c c c c c c c c ccccccc c %c c c c c c c c / c c c -c1Master Component List3c cc cc cc cc%c c/ cc-cc c cccccc c c c c c c -c c - c c " c c c " c c c c c 4/c c c c c c c c c c c c -c c c c c / c c c c c c c c c c c c -c c c c c cc c / cc #c cc c c c c c c cc cc ccc ccc ccc c c Figura V.V c c - c c & c c c # c c 2 c c 7 c c c c ccc2 c c7 c c cc cc-cc # c c c c -c c c c c c2 c c 7 c cc 2 c c ccc ccc- c8cc2 cc7 c c c" cc-cc4/cccc cc" cc c c c c c c c c c c " c c c c ccc6c c c c c c Botón View Add Delete Copy Import Export Refresh Descripción #c c c c c c -c c c c c -c c c 9c c" c c c " c c c c c c c ccc c 2c c c c cc-c c cc c c - c c c c cAddc c c" c c c c -c c c c List-Vc c c c " c c c c c c 2 c " c c c c c c c c cccc cc-cc c :ccccviewccs ccc c cc cc -c c c + c c "c c c c c c c c cc 2c c c c c -c c c c c c c c " c " c c c c cc cc cc %+ c c c c c c -c 1 3c c c " c c c c c c % c c c c c c c c c cc cccc 2c c c c c -c c c "+ccc cc- cc c:ccc c c "c c c c c c c c c c c c c c c c %c cc cc; 2c c c cc-c c ccc c 2c " c cccc c cc cc 2c &c c c c c c c c c c c " c c cc cc " c c cc c ccc c V.2 Pantalla del Listado de Componentes (Component List Wiew) c - c c c " c c c c c c -c c c c " cComponents ccc c cc4/ccc cc cc -c c c c c c cc c c c c c Wiew c c c cc c ccSelectedc cc c c c c c c c Figura V.2 c c c % c c c c c c c c cc c c c c c c c c %c c c c c c c c c c c c c c c / c c c c c c c c c cc c c c c c c c % c c c c " c c c c c " c c c ccc c 6c c þc c c c " c Selected c c c c c c cc c" ccc cc-c1Component List View) cc cc cc cc cc c" cccccc cAdd Component. þc c c c " c Component by Type " c c c c c c c c c c c c c c 1 ccc3ccc c c 6ccc c c c c c c c c c c c c c Figura V.3 c c V.2.Vc Ingreso de Componentes de la Biblioteca c c c c c -c c c c " c c c c c c c cc-c cc%c c cc c c cc c c c c c c c " c c c c c c cc c cc c ccc" c c c c cc" cSelected cc c 6c c þc %cc c" cccc"ccc1Add Component 3c þc %ccc c1Selected Components 3c þc %c c c c c c c c c 1Components available in the Component Library3c c - c cccc c c c c c Recuadro de Ingreso de Componentes (Add Component Group) c %c cc ccccc#c cccc cc ccccc cc" ccc cc cc c c c ccc c cc c" . c c c c c c c c " Traditional, Electrolytes, Hypothetical, Otherc Recuadro de Componentes Components Group) Seleccionados (Selected Figura V.4 %c c c c c 1Selected Components3c c c c c c c c c " cc c c c c c c cc #c ccc c c c cc c c c c cc cc c" c 6c c c Objeto Descripción Selected Components %c c c c c c c cc c cc c 4c c " c c c c c c c c Add Pure c c c c c c c c -c 9c 1Available Components) c ccc c 4c c c c c c c c c Substitute c ccc c c c c c cc 4 c c c c c c c c Remove Component c c #c c c c c c c c c Sort list cc c cccc c c #c c c c c c c c c View Component c c c c c c c c c Recuadro de Componentes Disponibles en la Biblioteca de Componentes (Components Available in the Component Library Group) Figura V.5 c c c c c 4 c c -c c c c c ccComponentscAvailable in the Component Librarycc%cc cc c c c c c c c c c c c cc c c c c c c c c c c c % c cc cc c" c 6c c c Objeto Descripción #ccc c cc c c c c c Match ccc c c c cc c &c c &c c"cc%ccccc c "c %c c c c filter c c c "c View Filter Button c c c c c c c c c cc c c c c c c c c c c c c c c c c c 2 c c c c c c .c c 7 c c -c 0 c 1Filter Options for Traditional Components) c Sim Name/Full Name %cc c c c c c c c c cccc"cc c c Synonym/Formula c ccmatchc Show synonyms Cluster - c c c c c c c c :c c c c c c c c cc c - c c c c c c c show synonyms, c c c c c c c c c cccc &cccc c cc c cc c c c V.2.2c Selección de Componentes de la Biblioteca -c c c c c c c c c c c c c c c c cc c c c c c c c c c c c c -c c c c c c c c:cc cAdd Pure cc c cc cc&c cc c c cc &c c" cc c ccmatch. Filtrado del Listado de Componentes Seleccionado Teniendo como Filtro los Tradicionales s c c c c c c c c c c c c c c c c c c c c c c c c c c c c %c c c c c "c c c c c c c cc c c cc cccc"c c cc c c cc c c ccc cccc cccccc ccc cc'8<cc'8(cc c %c c cc cc ccccc c c c c c c c c % c c c c c c c c c #c c c c c 6c c Herramientas de Descripción Filtrado Property Package and 7 cc cc-c cc c c c 2 c c 2 c c =c c c Family Type Filter 7 c c -c c > c c c .c c 7 cc-c0 c cc cc c c c c c c Show synonyms c c c c c c c c c cc c %c c c c c c c c c Cluster c c show synonymsc c c c c c "c c c #c c c c c c clusterc c c c c c &c c c c cc ccccc Match % c c c "c c c c c c cc c cccc c c ccc c - ccc c c cccc c c cc c c cccccc c c c 6c c Botones de Radio Descripción %cc ccc" cc c cmatch c Sim Name cccc c % c c c c c c c c c c Full Name/Synonym c c c c c c "c c c cc c c - c cc c " c c c c c c c Formula c c ccc c 2c&ccc c" cc8.c c c ccccc8cc c c c " match. c c c c c c c c c c c c c c c c c c c " c c %c c c c c c 8c c c c c c c c " c c c c c c # c c c c c c c c c c c c cccc c Figura V.6 c c c 7 c cc c c ."c c" c c c .c c c c c match,ccc8.ccc cc ccc " cccc c c c c c cc:ccc c Opciones de Filtrado por Componentes Tradicionales c %c c cccc c c:cccccView Filtersccc c c cc c &c c cComponent List View cc ccc ccView c4/. 9cc cc c c c cccc c2 cc2 ccc7 cc-c."ccc c %ccc2 cc2 c ccc ccc cc c c c c c s c c c c2 c c 2 c c c c"c c c cc cc c ccc ccc c cc cRecommended Only, cccc c 6c c þc c c c :c c c c Recommended Only, c c " c c c cc ccc cccc cc cc-cc c4 þc c c cc>c.c cc c cc ccc c cc" ccc cc-cc c 4 c s c c c c c c c c c c c cc cc cc c ccc "c cc c ccccc c %ccccc7 c1Family Type Filter3ccc cc cc c cc c & ccc c c c cc c c c c c c c c c c c c c c c cccc cccc " c cc- c c c:cc c cc cUse Filterc c c cc ccc c c c c :c c " c c c c c c " c c c c c c c c c c c c c 7 c 0c 7c c #c c :c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c sc c c c c c c c c c c c c c c c c c c c c c cc Allc c c c c c c c c c c c c c c Invertccc cc c c c c c c cc c c c c c c c c 1Invert3c c c c c c c c c c cccc c Selección de Componentes 9 cc c c c cccc cccc cccc" ccc cccc c c cc" c c c c " c c c c c c c ccc cc6c c þc 2" c c c c / c cc c c c c " c :c c c c þc sc c ctabccshift tabc c c cc c cc c cc c 0 cc c cc c cc c1Arrows3ccpgcupccpgcdown,ccendcc home ccc c c cc cccc c c c Transferencia de Componente(s) c 9 cc cc cc-c9cc c4 cc cc c c c c c c c c c c c" c ccccc c 6 c þc " c:cccccAdd Pure.c þc 2center.c þc " cc:cccc cc/ c c %cc c c c c c c c c c c cc cc c V.2.3c Manipulación Seleccionado del Listado de Componentes 9 cc c ccc c cc-cc c c c c c " c c c c c c c c c %c c c c c c c c c c ccccccc c 2 c c c c c c c c c c c c c c c c 4/c c :c cAdd. c " c c c c ?'c c c c c 0 c c c c c c ? c c c c c c 'c c c c c c c c c c Add Pure c c c c c c c c cc Selected Componentscc Figura V.7 c Remoción de Componentes Seleccionados c cc2 cc "+cccc cc cc" c 6c c 'c > ccc cc c cc cc 8c c:ccRemove cc c cdeletec c c 2 c c c c c 4 c c c c c c c ccc c c cccccc c4 cc -ccccc ccc cc ccc c c ccc cc%c c cccc c c c c c c c c cc c c c cc cc-c c c Substitución de Componentes - cc ccc cc cc c c c c c c c c c %c c c c c c c c c c c c c c c c "c c c c cc & cc c cc cc cc c c c c c c c c c c c c c -c c c c c 4 c cc" c6c cc 'c > ccc cc c cc ccc c c 8c > ccc c cc c" cc ccc c cccc @c " c:ccc Substitutec <c %cccc c c cc c ccc" c ccccc c c c Organización de un Listado de Componentes c 2 c " c c c c c c c :c c c c c Sort List. # cc ccc "cc%cc cc ccc cc c cc c c ccc " ccc ccc c cc c c c c c c 2c c c :c cc c Movec c c c c c c:ccClose. Inspección de Componentes (View Component)c c s cÄ cc c c c cc-cc cc cc c c c cccView Componentccc cc9c c c c c c c c c c c c c c c c cc c c c c c c c c c c c c c c c cc2c&c c cc c cc cc cc c cc cccc ccc c c c c c c c c c c c View Componentc c c c c c c "c c c c c c c c c c2 c c c c c cc c c c c c c c c c 1Edit Properties3c c c c c c c c c c c c cccc c - c c c View Componentc c c c c " c c #c c c c cc c c c c c c cc c c c c " cc" ccc"c&cc ccc c cc cc&c cc ccccc cc ccc c cc cc c cc"ccc c ccccc c Pestaña de Pagina de Identificación (ID Tab) c c cId Tabcc c cc c ccView Component. c cc c c c c c "c c c c c c c c c c c c User ID Tagsc c c c c c c c c c c c c c c " c c +c c c c cc c c " c +c+cc c c cc c Pestaña de Pagina de Valores Críticos (Critical Tab) y de Propiedades (Props Tab) c % c c " c c " c c c c c c c c c cccc c c cc ccc c c c1> c.3ccc "ccc c c ccccc Edit Properties. c c Component Viewc c c c c c cc c c cc cc c cc c ccs c c cProps Tab c " c c c c c c c c c c c cc % c c cc c cc c cEdit Properties. Pestaña de Pagina de Propiedades Puntuales (Point Tab) c c c c c c c c c c2 cc2 ccc2c/ cc c cccc ccc ccccc% c c cc" ccc cc c ccccc c cc cc c c cc c cc2 c2 c# c c c c c c c c c c c c c c c c c c % c c c c c c c c Point Propertiescc c:ccEdit Propertiesc c" c c c cccc c Pestaña de Pagina de Propiedades Dependientes de la Temperatura (Tdep Tab)c c %c c " c c " c c c c c c c c c c c c c c c c c c c cc c c cccccc c c c c ccc cccc cc cc+c c cc cc% cA ? c1A%3cc%cc cc ccc c ccccc" c cccc "cccc c c c c c c c c c c c c c c c c c c c c c c c c c c Edit Propertiesc c c Pestaña de Pagina User Prop & PSD c c " c User Propc " c c c c c c c c c c ccc ccc" cc c cc4/cc c c c" ccUser Property. s cc cc" c c ccc c c c c c c c c c c c c c c c cUser Prop. c cPSDc" c c cc cc c ccc2c cc c c29Bcc cccc c cc29c " c c 2 c c c29c cc cEdit Propertiesc c c c c c c c c c c c c c c cTypec c c c cSort Byc c c Particle Size Distribuciónc c c c c c c c ccc ccc cc c cc c c Figura V.8 c c c c sc29c ccccc 6c c Input PSD Group Descripción 2c c c" c cccc c User-Defined Discrete c c c c "c c c c c 2 c " c c c c c c c Edit Discrete PSDc c c c c c "c c c c c c c c c c cc &c c c ccc ccc c cccc c c c c c c s c c c c " c c c c c 29c c c c c c c c cc29c c cc & c c cc%c cc " ccc cFit Type ccc & cc Log-Probability Rosin-Ramler c c %c c c & c c c c c c c cc" c c cc"cc cccc %c c c ccc c c c c c c c c c c cc29c c c c c c c 29c cc c c c c c c c c c +c c c c c c c " c c 29cc c c c c c c c c c c c c c c c c c c 5"c c 9 c c 29c c c c " 6c c Input PSD Group Descripción %c 29c c c c c c c c User-Defined Discrete c c +c c c c c c c 29c c c c c c c c c c c c c c c c c c c c 5csc c.c %c 29c c c c c c c c Log-Probability c c +c c c c c c c 29c c c c c c c c ccc c c c %c 29c c c c c c c c Rosin-Ramler c c +c c c c c c c 29c cc c c c c c c cccc c %c cc ccc "ccc ccc cccc c c c c " c c c " c c c c c c "c cccc ccc6c c þc sc c c c c c c c c c c " c c cc cc c c þc sccc cc c" c c cc&c c c c cc2c&cc c c cc c 1&c c c c c c c c c 3c c c c c c c c c c c c c c>?> c þc #c c c c c c c c c c c c "cc cc &ccc cc2 c cc cc c cc c c cc ccccc c cc2c c c ccc cccc c %cc cFit Type cc c cc"cc ccUser-Defined Discrete c c c & c c c c c c c c c " c c c ccc%c & c& c ccc ccc c c c+ c c þc 5 c c c +c c c c c c c c c c c c c c c/ c c cc c cccc ccc cc+ c c þc 2c cccccc cc c c c c %c c c & c c Fit Typec c c c c c c c &c & c c c c c %cc "c c & c" c c cc "ccccc & c c c cc %cAutoFitc"c c cc & c c c c cccNofitccc & c c c c c %c c Estándar c c c Probability c c " c c c c " c c c c & c c c c c c c c c c c c c c c c c %c " c c c c c c c c cccc c c cc " c c c&cc c c c c c c c c c c c c " c c c c>?> cc2 c cc c c cc & c>8c17"c7 3c c cc cc c c c&cc & cc7 ccc c c c c c c c c c c c c c c c cc c" ccs cc c cc29c c ccc c ccc cc cc cc c c Edición de Propiedades (Edit Properties) %c c c c c c c c c c c c c c c c c c c c c c cc c c c c c c c c c c c OLI c c c c c c c c c c c c c c c c c cccc6c c þc Nivel de Componentes: " cccc ccc cc c c c c c / c c c c c c Select Viewcc "c " ccccccEdit Properties. þc Nivel de Paquete de Fluidos: " c c c c c c %c 2c c c cc7 c2 : " þc Nivel de Corrientes: c c c c c c c c c " cccccccc cc c& cc c c c c c c c c c c c c " c c c cc c c Figura V.9 c c c c c cc c c c " c c c c c c cc ccSort By c cccc c c c Sort By Descripción ." c c c c c c c c c Property Name c ." c c cc" c Group ." c c c c c c c Type c29cc c ." c c c c c c c c c Modify Status cc cc ccc c c c c c c c c c c c c c c c c cccccc cc cc cc%c c c c c c c c c c c c c c c cc c c c cc- c c c c c c c c c" c ccc cc c c " c ccccc cc%c c cc c cccccc cc ccc c #cccc ccc ccccc" 6c c Component Level Reset Reset Selected Property To Library Defaultc Reset All properties to Library Default Reset Selected Property for all Users of this Component Reset All Properties for all Users of this Component Descripción > c c c c c c c c c c c c " c c c c c c c %c c c c c c c c c c ccccc > c c c c c c c c c c c c c c " c c c c c c %c c c c c c c c c cccccc - c c c c c c c c ccc ccccc cc cc ccccc2 cc7 c ccccc - c c c c c c c c c c c c c c c c c c cc ccccc2 cc7 c cc-ccc c %c " c c c c c 2 c c 7 c c c c c c c c c c c c c c c % c c c c c c c c c c c c ccc c cc- c c cccc c cc c " c c c c " c c c c c c c cc c cccc cc ccc c 6c c c cccc Fluid Pkg Level Reset Descripción Reset Selected Prop - cccc c ccc c Vector to Components c c c c c c c c c c cc Defaultc Reset All props to - c c c c c c c c c c c c c c c c c components Default c cccc Reset Selected Property - c c c c c c c c for all Users of this fluid c cc c c c c c cc c c c c c c c c package cccccc cc ccc c c cc c c Reset All Properties for - ccc c c cc c c all Users of this Package c c c c c c c c c c c c c c c c c ccccccc cc c cc cc cc c ccc c %cccc cccccc c c c c c c" ccc cc ccc c ccccc c c c c c cc ccc cc cc %c c c c c c c c c c c c c c cc " cc &ccc c c c c c c c c c c c c c c c cc cc c ccccc cc c Reset Selected Property - c c c c c c c Vector for fluid package c c c c c c c c c cc ccc Default Reset All Properties to - c c c c c c c c c c c c c cc cc Fluid Package Default c c c c c c c c c ccc c c cc ccc ccccccccc c "cc ccc cc c c > c c c cccccc cc cc c cc cc c cc cc2c&cc ccc c c c c c c c c c c c c c c c c cccc cc c cc c cccccccc c c cc c cccc cc cc cc cc ccc c c c c c c c c c c c c c c c ccc c ccc V.2.4 Ingreso de Componentes Electrolitos c c c c c c" c c c c -c c c c c c c -c c %c c c c Add Componentsc c c c c Selectedc c c " c c c c c " c c c " c c c c %c c c c c c c cc c cc ccccc c ccc c" cc cc" cccc cc ccc cc"cccc c cSelected. ccc c ccccccc c" c c cc Filtro Match None Full Descripción % c c c "c c c c c c c ccccc c ccc c c ccc" c c cc ccc c c !"+c c c c c c c c c c c c c c c c c c c c c c c c c cc c c c c 7 c c c c c c c c cc ccc cc c c c.5c Limited % c c c c c c ')))c c c c c c c c c c ccc c c c c c c c c c c c c c c c ccc cccc c cc 6cC%.-%/c .D0%/2c >%9.$c c c c c c c c c c c c c c c c Additional Databasec c c c c c c c c c " cc cc cc c c cc" c c cc.5cc4 cc 9 c# cc%c ccC%.-%/c.D0%/2cc>%9.$cc cc c ccFull 9 :cc cccc c V.2.4c Ingreso de Componentes Hipotéticos c c c c c " c c c c c c c c c c c c -c 1Component List View3c c %c c c Add Componentc c c c Selectedc c c " c Hypothéticalsc c c c " c c c c c c c c c c c c c c c c"cccc Figura V.9 c c c #" c c c c c c c c c c c c c c c c c c c c c c c c c c c c cccccc c 6c c c c Objeto Add Group Descripción 5" c c c c c c c ccc cc" ccc c c c-c c 5" c c c c c c c c Add Hypo c c c c c c c c c-c cc cc c %c c c c " c c c " c c c Hypo Group c cc cc c c %c c c c " c c c c Hypo Components cccc" cccc ccc ccc" ccc %c c c c c c c cHypothetical c 4/c Hypo Manager c c c c c c c c cc Quick Create a sc &c c c c c c c c c c c c ccHypotheticalc c4/c c c Hypo Component c c " c c c c c c c cc c cc c Quick Create a sc &c c c c c c c c c Solid Hypo c c c c ccHypotheticalcc4/c c c c c " c c c c cc c Componente cc c cc c V.2.5 Ingreso de Componentes desde un Listado Existente c c " c c c c c c c c c c c Otherc c c " c c c c c c c c c c c c cc c cSelectedc c %c c c c c c c c c c c c c c c c c c " c c c c c cc - c c c c c c c c c c " c c c c c c c c c c c c c c c Selectedc c ccc c c 2 c c c c c c c c c c c c c c c c c c c c c c c c ccc ccc c c cc" c c c cOthercc c ccccAdd. %cc c" c c ccc c c Figura V.VV c c c c c c c c c c c c c c c c c c c c c c c c c c c c c 2c Paquetes de Fluidos 2.Vc Introducción %cc c c c cc cc cc c c cc c cc ccc cc cc%c c cc cc c ccc c c c cc c cc c c c c c c c c & c c c c c c c c c c 6c þc 0 c c c cc c c c c c c c c cc cc cc c c þc c2 cc7 c cc cc cc c cc c c cc c c þc c 2 c c 7 c c c c c c c c c c c c cc2 cc7 c-&c þc c c c c c2 c c7 c /+c c c c c c ccc "cccccccSBM. %c c c c c c c c c c c2 c c7 c c cccc c c cc c2 cc7 c c c c c c c c c c c c c -./0c c c 7 c c c c c c c c 2 c c 2 c 1Property Package View3c c c c c c " c c c " 6c c þc Set Up þc Parameters þc Binary Coefficients þc Stability Test þc Phase Order þc Reactions þc Tabular þc Notesc c c c c c c c c c c c c c # c c 2 c c 7 c c /c c c c c c c & c c c c c Componentsc c c c c SBM 1Simulation Basis Manager3c c %c c c c c c c c c " c c c c & "c c c c c c c c c c c c c1>c c- c 'c c c ccc# cc-3c c 2.2 Pagina de Paquete de Fluidos (Fluid Pakages Tab) c c" cc c cc c ccSBMcc ccFluid Pkgs. C cc c c c c c c c" c c c c " cc c2 c c 7 ccc c c 6c c Figura 2.V c c c c %c c c cc c c c:ccFluid Pkgscc ccc c c " c c c c c c c c c c c c ccccc%cccc c" c 6c c Botón Descripción %c c c c c c c c c 2 c c 7 c View c c c c c 2c c c c c c c c cc " cc cc c c 2c c c c cc c c cc c Add 2c c c cc cc cc cc- cc Delete c c c cc cc c c cc c ccc c c c c ccc cc cc c c2 c c7 c c c c c c cc c c c c c c c c c c c 0c c Copy cc c" cc c cc ccc% c c c c c cc cc cc c 2c c c c c c c c "+c cc Import c c cc cc.fpkc 2c c c c c c c1*.fpk3c c "+c Export cc%c cc c cc c c c"c c c cc cc c c cImportc c 2.3 Ingreso de un Paquete de Fluidos-Ejemplo - cc cccccAdd c c cc2 cc7 c1Fluid Pkgs3c c4/cc c c c c c c2 c c2 c c c" c c c cSet Up. c c cc ccc cc2 cc7 cc cc c c ccc Figura 2.2 c c c %ccc c cc" cc c cc2 cc2 cc7 c c" c c c cccc c ccc cc c &c c c c c c c c &c c c c ccccc2cc 6c c þc c c2 cc2 cc c cSet Upccc cc c c c c c 1Property Package Selection3cc 2c c c c c c c 2 c c 2 c c ccccc ccc cc7cc2 c c2 c1cProperty Package Filter3cc#ccc c c c ccc cc cc c cc cccc c c c c c c c c c c c c 4/c c c c c c c c c c =c c þc 9c c 2 c c 2 c c c c c c c c c cc% c/ccA c c cc2"cc þc 9c c 2 c c 2 c c c c c " c c c c c c c c c cc %cc cc c cParametersc þc cc c c c c c c c c c Binary Coeffs. -c c c c c c c c c c c c cc ccc þc c c c c c c c c c c c c c cc ccc cc c cc c cStab Testc þc 9 c c c c & "c c c c c c c c c c c cc c1Reaction Manager3cc c cRxnsc þc %c c c Tabularc c c c c 2 c 0 c c c c cc cc c c cc þc c c cc c cc2 cc2 cc7 cc cc Notesc c c c c c " c c c c c2 c c7 c c c c c c c c c COMThermo c c c c c c c c c cc cc cc cc c cSet Upcc c c c c " c c c c c c c c c c &c c -./0 c c Figura 2.3 c c c c %c c c c c c c c c 2 c c 7 c c c c cCOMTherm c c cc c cc c c cccccc" 6c cc þc %c c c Set Upc c c c c c c c c c ccc c c c cc" cc c þc 9c c c c c c c c c c c 2c &c c c c c c c c cccc c c c c-cc cc cc ccdrop down listc þc 9c c c c c c c c c c ccccc c cc%cc c c c cc" Parametersc þc c c c c c c c c c c Binary Coeffs. -c c c c c c c c c c cc cc ccc c þc cc c c cCOMThermocc cccc c c cc ccc cc c cc c cStab Testc c c 2.4 HYSYS Pantalla de Paquetes de Propiedades de Fluidos c cc2 cc2 cc7 cc cc cc" c c c c c c c c c cc c c c c c " cc c ccc c c c cc c c2 c c7 cc c7" c8<c" c c cFluid Packagecc c cc c c cc c" c c c c c c Figura 2.4 c c c c 2.4.Vc Pestaña de Pagina Set Up c cSet Upcc c cc c cc" cc c ccc2 c c7 cc- cc c c cc c c c c cc cc cFigura 2.4cc#c ccc c cSet Upc c c c c" cc cccc2 cc2 c c cccc c c c c c c c7c c2 c c2 c cc c c c c c c c c c c c c c c c c c c c c c c -./0c s c c c c c c c2 cc2 ccc ccc cc " c c c c c c c c cc%cc c c c c 7" c 8<c c c c c % c c /c c % c c % cc% ccEOSc1Equation of State, Enthalpy Method Specification3cc%c c Figura 2.4c c c c c c c c 2 c c 2 c cPeng Robinsonc c c c cc c c c c c c c c c Peng Robinsonc c c c c c c c c c c c c c c c " c c c c c c c c c c c c c c c c c c c c c c c c c c c cc c ccc c c c" cccc cc cccc c2 cc 7 c c c c c c c c c c " c c c c c cSet Upc Selección de Paquete de Propiedades %c c ccSet Upc c c c cccc cc c c c c c c c c c c c c c c cc c ccc7cc2 cc2 c c %c c c 7c c 2 c c 2 c c c c c c cccc ccc" c6c c 7c 9c 0c c /c c 2 c c 2 c c c All Types c c c c% cc% c ccc c EOSs c /c c -c c # c c c Activity Models ccc c Chao Saeder Models c c c c c c - c c c c c c Vapor Pressure c c c 2c c A c c c c Ec c cc c Models cc ccc & c c c<c " cc c Miscellaneous cc Para mayores referencias sobre los paquetes de fluidos disponibles en el HYSYS, referirse al Apéndice A- Métodos de Cálculo de Propiedadesc c c Ecuaciones de Estado cc 2 c c c c " c c c c c % c c % c c 2"c >c c " c c c c c c c c c c %c & c c 2>.0%-c c c c c c c " c c c c c c c c " c c c c c c "c c c cc> c c c" c c c c c c c cc c c c c" cc cc c c 0cc cc cc cc c c ccc &6cc c EOS´s Descripción % c c c c c c c c c GCEO´s c c c " c c c c c c c " c c c c c c c c %c c c c c c c c c c Kabadi Danner Lee-Kesler Plocker Peng Robinson PRSV SRK Sour PR Sour SRK Sudkevitch Joffe c ?>?E,"c 1>E3c " c & c c c cc cc ? c1A%3c c c c c ccc "c c %c c c c c" c c cc c cc cc cc c ccc %cccc c c cc%Acc c c c c c c c c c c ccc c c cc& c cccccc c "cc cc c c c c " c c c cc c "c c " c c c c c c cc cc cc/cc# cc 2"?>c :c A c c c c c c c c c %.c 2"c >c c c c c c c ccc c %c c c c cc cc ?>cc E,"cc c c ccc2>cc c "cc cc cc cc%cc cc c c c cc c - c c cc c2>ccc c c c #25ccDc cc &cc c c cc - c c cc c>Ecccc cc #25ccDc cc &cc c c c %c c c c c c c c >Ec c % c c c c & c c c &c c c c c c ? ccc cc c " c c Modelos de Actividad c # c c cc c c cc c c c cc c c cc c ccc cc c cc c c "cccc c c cc c c c c c c c c c c c c c c c c c &c cccc# c c #c cccc" c cc c ccc c c ccccc6c c Modelo de Actividad Descripción 2c c cc &cc c c/c Chien Null c # c c c c c c c c c c c c 2c c c &c c c c c c cc cc c c c c /c !>0c 1Non Random Two Extended NRTL Liquids3cc" c cc c#&c4&c-&c c #8&c c c c c c c c ccc ccc c c 6c General NRTL Margules NRTL UNIQUAC Van Laar Wilson þc 0" c c c "c c c c c c c þc > c c c c c%Ac c %c c c c " c c "c c c c ccc ccc % c c c /c !>0c 1Non Random Two Liquids3cc cc cc c cc cFccGccc ccc c c 6c þc 0" c c c "c c c c c c c þc > c c c c c%Ac c %c c c c " c c "c c c c ccc ccc % c c c c c cc%cc %" cCccc% c ccc" c c c c c c +c c c c c c c c % c c c c c c % c c Dc c s c c c c c c c c c c c c c c c %c c c c c c c c c c c c c c ? c c ? ? c 1%Ac %c %A3cc s c c c c c c c c C ""c c c c c c c % c c c c c c c c c Ac c c Ac c c c c c c !>0c c c c c c c c c c c c cc % c c c & c c c c c c c c c cccc c c c c c c c c c c c c c " c c c c c c c > c c c "c c c c c c c c c c c c 2c c c c c c c c-c " cc c %c c c cccc cc c c c c c c c c c c c %cc%" cCcc.c c cc c c c c c c c c c c c c c c c c c " c c c c c c "c c c c c c cc ccc c c c Modelos de Chao Seader & Grayson Streed c c c c - c c c C cc c c c c " cc %c c C c c c c c c - c c c c c c c "c c c c c c c c c c c c c c cc c c c cc%c c c ?Ecc c c c cc cc c c ccc c c Modelo Descripción s c c c c c c c c Chao Seader ccc'())c cc "cc cc)c c())c c > c c ccc cc cc c Grayson Streed cc"c Modelos de Presión de Vapor ccccc cc ccEcc c c c c c c & c c c c c c c c c c c c cc cc cc cc c cc cc c c c c c c c%c c c c c c c c c c c c c c c " c c c cc cccc c Modelo de Presión de Descripción Vapor %c c c c c c c c & c Antoine ccc c %c c c c c c c c Braun KV c c c & ccc%cc c ccc" cccc4 cc c c cc c cc ccc cc Ecc c c c cc cc c')c c %c c c c c c c c Esso Tabular c c & c c c %c c c c c c c c c c c / ,? 4c ccc Misceláneos c" cccc2 cc2 c cc+cc cc & c ccc cc%ccc c 6c c c Paquete de Descripción Propiedades -c c c c c 94c Amine Pkg >c c c c c c c c c c c c c c AMSIMc c c c c c c c 2 c c c c cc ccc % c "c c c c c c ASME Steam c " ccs c0 ccA cc c#/%c NBS Steam MBWR OLI Electrolytes 1# ccc/ c%"3cc c'H*Ic % c "c c c c c c c " cc s c0 c c A c c c !4c 1! c4c3cc c'HJ<c % c c c c c c c " c c c c 4?D?> c c % c c c @8c cc cc cc cc c cc c c c c c c c c c 9 c c .5c c 5c c c c c c c c c c cc cc cc c c c Selección de Listado de Componentes c c c c "c c c c c c c c c 2 c c 7 ccc%cc ccc cc ccdrop down listc c c c c c c c c c c c c c c c c c c c 2 c c 7 c c c # c c -cc ccc cc=cc c c " c c &c c c c c c c c c c c c " c c c c c c c c 2 cc7 c cc c #c c c c c c c 2 c c 7 c c "+c c c c c c c 2 c c 7 c c c c c c c c c c No se recomienda adjuntar la lista o listado maestro desde la biblioteca a ninguna de los Paquetes de Fluidos. Si solo el listado maestro existiese, HYSYS crea una versión clonada del mismo llamada Componente List-V, que es la que se selecciona inicialmente cuando se crea un Paquete de Fluidos Mensajes de Advertencia %c c c c &c c c c c c c c c c c2 c c7 cccc% c c c c c c c c c c c c c 2 c c 7 c c c c c c c c c c c #" c c c c c c c c cc c cc cc ccc c cc c c c c c ccc cc cccc cc%c cc c ccc c cc ccc c c c cccc c c c c c cc c cc c c c c c c c c c c " c c c 6c c Figura 2.5 c c c c &c c c c c c c c c c c c ccc c 6c c c Objeto Descripción Not Recommended c c c c c c c c c c " c %c c c" cc cc c c Desired Prop Pkg c c c c c c c c c Not Recommended cc . c % c c c c c c c c ,c c c c c c c c c c c c c ccc c c c c ccc c2 cc7 c c cc c %c ccccc 6c Action þc Delete components c c c cc2 cc7 þc Keep Components c ccccc 2 cc7 # c c c c c c c c c c OK c - c c c c c c c cc c cc2c Cancel 2:"cc c"+c c c %c " c c c "c c c c c c c c c cccc c c c c c c2 c c7 c c c c c c c c c c c c c c " c c 6c Figura 2.6 c c c c c&cc c cc "c c ccc c 6c c Objeto Descripción c c c c c c c c c Incompatible " c Components %c c c" cc cc c c Desired Prop Pkg c ccc ccc ccIncompatiblesc cc c % c c c c c c c c ,c c c c c c c c c c c c c ccc c c c c ccc c2 cc7 c c cc c # c c c c c c c c c c OK - c c c c c c c cc c cc2c Cancel 2:"cc c"+c c Opciones Adicionales de Paquetes de Propiedades - c cc c c c2 cc7 cc c" c cc c cccc ccc ccc c cc c cSet Upcc% c cc cc cccc2 cc 2 c c c %c ccc c c c c cc" cc ccc c ccc c cc cc c c cc c c & c c c c c c c %.Bc c /c c # c c c c cc c c c c c Paquete de Propiedades Equations Of State Activity Models Amine Pkg OLI_Electrolite Especificaciones y Opciones % c c c /c c % c c %.Bc 1%.Bc % c /c 3c 2"c >c .c % c c /c c 9 c c 9 c c c c c c c %.Bc 1%.Bc 9c cc c9c 3c % c c/cc# c .cc# c1#c.3c þc /c 0c c c c cc " c þc /cc7 cA c .c c %c c .5c 1.5K%c .3c Especificaciones de los Métodos de Entalpía con EOS´s c c2 cc7 cc?2:c1E23cccL :cMc1LM3c cccc c c ?2:c c !c c c c c c c " c c c cc ccc c -c c c c c c c c cc c "c c c c ccc cc c" c 6c cc Método de Entalpía Descripción -cccccc cccc c c Equation Of State c c cc c cc %c c c ?Ec c c c c c c Lee-Kesler c c % c c c c c c c 2 c c c c s c %.c 1 c c c cc%.3c c c cc cc ? c c c c ?Ec c c c c c c cc%c c c cc c c c c c c c c c c c c c "cc cc Especificaciones del Modelo de Actividad c %c c c c c c c c c c c c c c c c c %c c c c c c c c c c c cc c" c" c Figura 2.7 c c c ccc cc& c cc c c cc cc c c c c c c c c c c c " c c c c c c ccc ccc c c cccc c c cc 2 cc7 c"c c c cccc c c/cc7 cA cc c c cc ccc,ccc c c 6c c Vapor Phase Descripción Models %c c c c c c c c c c Ideal c cccc & cc c c ccc c+ c" cc>?E,"c RK c c c c c c c c c c c c " c c ccc" c 2c c c &c c c " c c c c c Virial cc c c c c cc c c " c c %c c c c c c c c c c c c c c c c c c cc c cc c c" c s c c cc cc2"c>c c c c PR c" ccsc cc ccc ccc c2>cc c cc s c c c c c c ?>?E,"c c SRK c c c " c c sc cc c c c ccc c2>cc c cc ccc c " c c c c c c c c c c c c c c c cs!57#-cc% cc c c cc c c c c cc c cc ccccs!57#-cc2cc c c c cc c c 8(c " c " c cc c &c c c c c c c c c c c c c c c %cc cc ccc c c c cc c cc c c c 7 c c-c 2"c c % c c c c c cc c c ccccccc ccc cc cccc%c cccccc c c c" cc c cc c c c c c c c c c c c c c " c c c c cc" c c c c c Opciones del Paquete de Aminas c" ccc ccc c cc c cc cc 2 cc# c1Amine Pkg3c c c c c Figura 2.9c c c %c ccc "ccc ccE?%"ccc/ c c c c cc cc " cc> c c#c-<? cc% c c cc cc ccc%ccc cc c cc c c c c" cc ccc c c" cccc ccc c Opciones del Paquete OLI_Electrolyte c c c c 2 c c 7 c .5K%c c " c c c c ccc c 6c Figura 2.V c c 9 cc c c c ccccc c c cc c c c c c %cc c c c c c c 1Initialize Electrolyte Environment3cc c cc" 6c c þc C c c " c c c c c c c c cccc cc ccc7 cccc cc c7" c8')c þc C c cc cc c cc c c c c c c c" c c c c c c c c c cc c cc c cc c cc cc c c c c c c c " c c c c c c c ccc cc c cc c c ccc cc c c c c c c c c c c c c c c c c c cc c& cc c" ccccc ccc c c c c cc ccc c c c c c c c c c c c c c c c c c c c c c c c c c c c ccc c 6c c c Fases Incluidas Descripción C c c c c c cc c c c c c Vapor y Sólida c c c" cc cc c c c C c c c" c c c c c c c c Orgánica y Sólida c c c c cc cc c c" cc C c c cc cc" c c cccc Vapor y Orgánica c c c c cc cc c c c C c c c c c cccc c c c Solo Vapor " c c c c c c c c c c c c c c c cc cc c c c C c c c" c c cccc c c c Solo Orgánica c cc cc c c" ccc c c c c cc cc c c c sc c c c c c " c c " c c Solo Sólida cccc c c c %c c c c c c c c c c c c c c c ccc1Selected Solid3cccc c ccccc c c c c c c c c c c c Exclude All Solids. 2c c c c c c c c c c c c c c c c c cccc cccc c c c c c 2 c c c c c c c c5 c c %c % c c c c cc Initialize Electrolyte Environment c "ccccccc c1Selected Solids3cc- cc c:c cccc c ccccc cc c c c c c c c c c c c c c c - c c c c c c c c c c c 1Electrolite Environment3c c c c c c c c c c 0 c c7 c c 9c 1All Scaling Tendency3cc ccccc ccc cc c ccc" c ccc cc c c c - cc c c c c %c c ccc Initialize Electrolytecc cc c c > c% c 1Electrolyte Reaction3c c c c c c c cc cc%cc c c c cc ccc ccc c cc c cc c 2.4.2 Tab) cc Pestaña de Página de los Parámetros (Parameters c c c c c c c c c c c " c c c c c c Parametersc c c c c c 2 c c 2 c c #" c 2 c c 2 c c c c c c c " c c 2 c c c c " c c c c c c c %c c cc cc2 cc2 c c cc c c c c cc c cccc c c "+c c c c c c c c c c c &c c c c c c Ecuaciones de Estado Cúbicas Generalizadas (GCEOS) c c % c c % c -+ c C c c c c c c 2 c c 2 c c c c c c c 2c c c c c c + c c c c cc cc c Figura 2.VV c c 2 c c c c c c c c c c c + c " ccc cc c cc c 6c c c ù c c c 2cNc ?c cc c % c18'3c c c ccccccccccccL@O-'L8O-8LO-@cNc)cc c c % c1883c c c c c ccc6c -'cNc4 cPc4cPc'c c c % c18@3c -8cNc48 ,cPc48 cPc4 cOc#c c c % c18<3c -@cNc?14@ ,cOc48 ,cOc#43c c LcNcù cc c c c c % c18(3c c c % c18(3c c #cNc c 4cNc ù c c c c c c c c c c c c c c c c c c c c c ù c c c c c c % c18*3c c c c c % c18I3c c % c18J3c cNcQQ& cc c c c c c c c c c c c c ccccc cË 1 c ccccccccccc ccNccRAc c 5 ccNcc c c c c % cc18H3c c c c % c18')3c c c 103cNc G cc c c c « « cO 3>0Acccccccc cccccccccccc% c18''3 c c ccc c c c c ccccccccccccc% cc18'83c ! 8cOc@ R8cOc@RcPc'c ccccccccccccc% c18'@3c c c c c ccccc/>&cNc c" cc c c %c 103c c c% c18')3c cc ccccG6c c c G103cNc"# $%# &'() *+8c c % c18'<3cc c c c c Gcc c cc cccccScc%c cScc ccc c c c c c c (c c c c S'c S8c S@c S<c c S(c c %c c S)c c c c c c c c c c Gc c c c ccc cc cc%6c c c ScNcS)cOc¥ « ù # ù, -cc1'Ocù'() 31)Ic?cù 3cc ./ c c ccccccccc ' Nc#cOc4ßcOc-ß8cO9ß8 c c c c c " c Parametersc c c % c c % c - c C c 1C-%.3cccc cc" 6c c þc 2 cc cC-%.c cc c þc 2 cc cC-%.c þc 5 c%.c Parámetros de la GCEOS para Componentes Puros % c c c c c Parameters c c c c c c c Gc cc ccS)c cS(ccc c 2 c cS)c cccc c: )cc c c c c cc c 7" c8'8c cc%c ccc c c cc<c cc c Ecuación 2.V56c #c 4c-c c 9c c c c c c c c c c 2 cc7 c c Figura 2.V2 c c c 2 c cc c c: cc ccc c: '?(cc s c c c c c cc c7" c8'8c cc c c c c " c c c c : c c c c c c c c c c 2 cc7 c c Traslación de Volumen c c % c c % c -+ c C c 1C-%.3c c "c c c c c c cc c&c cc c c c cc c%.c + cc cccc c c cc "cc&cc c c c c c &c c c c c c c c c c % c A ? c 1A%3c c / c c c c c c c c " c 6c c c cccc c c F cNcc?c0 c c c c c c c 6cccccccccc c c c c c c 1 2 43 3 c F cNc c c 1 ccNcc cc c c c c 5 cNc c ccc cc cNc c cccc c c c c c c c c c c c c cc c c cc c%cuaciones 2.5, 2.6 y 2.7cccc cc ccc cc cF cc1 c c 2 c c c c c c c c c c c c c cccc cc c c cc c cc c c c c c c cc c7" c8'<c c c c c c c c c c c c c c c c c c c c Figura 2.V4 c c c c %cc cc" c c cc c ccc" cc cc c c c c c c c c c c c c c c c c c c c c c c " c c c c c c c c c c c c c c Estimate. c c c c c & c c c c c c c c c c c c c c c c c c c c c c -.0#9c Cuadro de Parámetros de GCEOS c cc c7" c8'<c" c c c c c c c c c c cc2 cc2 cC-%.cc%c cc c c c cc,c cc c% cc8@c c8'(c c c " c c c c c c c c,c c " c % c c % c 6c c EOS u W )c )c Van der Waals 'c )c Redlich-Kwong 8c ?'c Peng-Robinson ccc c Barra de Estado de la Ecuación c c c 2 c c c C-%.c c c c c c c c cc cc ccc c ccccc &cc cc c c 6c c Mensaje %.c!.0c>%#9c %.c>%#9c Descripción %c &c c cc cc cc,ccc c cc c cc cc,cc c c%.c cc cc cc c c Inicialización de EOS c c cc ccc,cc cInitialize EOScc c c" cc ccc ccc cc c%.c c c c ccc c" 6c c þc % cA ccD c þc % c>Ec þc % c2>c þc % c2>Ac12"?>c&:cA 3c c Kabadi Danner c %c 2 c c 7 c E c 9 c c c c c c ccccc ccc cc" ccccc 0, ccc" cc c c c cc c" c8'(c c c c c Figura 2.V5 c c Peng-Robinson Stryjek Vera c c c2>Ac c c c c : c c & c c c c c c ccc" cc c7" c8'*c c Figura 2.V6 c c c c Zudkevitch Joffe c %c 2 c c 2 c c c c c " c c c c c c c cccc cccc cc c c Figura 2.V7 c Chien Null c %ccc-c! cc c cc &cc c cc c c c c c c c c c %c c c c c c c c c /c c c c c c c c c c c c c c c c c c c c c c c cccc c cc cc c ccc2 cc2 ccc" 6c c þc 2 cc-c-cc! c þc 2 cc-c4 c-c! c c Parámetros de Componentesc(Component Parameters) c cc cccc cc c cc cc c c cc" cccc c c cc c7" c8'Jccc c c c " c c c &c c c c c c c c c c c Figura 2.V8 c c c c c c c %c c c c c c c c c c " c c c c c -c! cc c c>" cc ccc/cc# c c c c cc c4 c c Parámetros de Componentes Binarios c - c c c c c c c c c c c c c c c c c c c c c c c c c c cc c c cc c cccc c c c þc Liq Activity Models þc Virial Coefficients c c Figura 2.V9 c c c - c c c c c c c c /c c # c c c c c cc/cc# c cc c cc cc c cc cc5 c c ccc2 cc2 c c c c c c c c c c c c c c c c c c cc cc c cc c ccc cc ccc cc c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c cc c c %c c cc c7" c8'Hcc c cccNRTL (Non Random Two Liquids)c c c c c c c c " c c c c c c c ccc c cc c c c c c cc c c ccccc c c c cc cc c c c c c .c c c c c c c c cc cc c ccccc+ c c cc c cc c ccc cc c cc c c #c cccc cc-cA cc" c ccc c c c c c c ,c c c c c c c c c ccc ccc c cc c cc/ccA c A cc c ccSet Upccc c& cc c ccc c c c c c c c cc c c c c c " c cc "cc c " cc c c c ccc c c c c c c c c c c c c c c c c " cc cc " c c Wilson c c c c +c c c c " c c c c cWilsonc Component Parameter c c c c c c c c c cc c c c Figura 2.2 c c Chao Seader & Grayson Sreed c %c c c - c c Tc C c c c c c c c A c / ccc c c c A c / c c # cc c c c c c c c c %c c c c c c c c ccc Figura 2.2V c c Antoine c c ccc#ccccc cc7c&cc2 c c c c c c c " c c c c c c c c c #c c 7c c c c c c c c c c c c cc ccc ccc&ccc ccc Figura 2.22 2.4.3 Pestaña Coefficients Tab) de Coeficientes Binarios (Binary c c c c -c 4 c " c c c c c c c c c c c c c c c c 9c c /c c 2 c cc" cccc ccc ccscc cccccc cc c c c c c c c c c c c c " cccc - c c c c c c c c c c 14/3c c c c c cccc c ccccccc c 2 c c c c c c 2 c c -c 4 c c c c cc "cc c c cc c c c ccc U cccc c cccU& c c Parámetros de Interacción de la GCEOS c - c cC-%.ccc2 cc2 c cc c cSet Upc c cc-c4 c ccc c c 6c c c c c c c c Figura 2.23 c c c %c 2 c c 2 c C-%.c c c c c c c c c c c c c c c c c c c &c c c c c" c" c" cc 6c c % c18'J3c cc c c c c c &c Nc cc/>&c c 6cccc/>&c Nc c>" cc/ cc2 cc c %ccc c cc c c c/>&6c c Ecuación ccccccccccccccccccccccccccc />&103cNc1'?c#&cOc4&0cOc-&083cccccccccccccccccccccccccccccccccc cc% c18'H3c ccccccccccccccccccccccccccc />&103cNcc1'?c#&cOc4&0cOc-&=03ccccccccccccccccccccccccccccccccccc % c188)3c ccccc/>&103cNc'c?c1'?c#&cOc4&0cOc-&083c?c&1'?c#&cOc4&0cOc-&083cccccccccc% c188'3cccccc ccccc/>&103cNcc'c?c1'?c#&cOc4&0cOc-&=03c?c&1'?c#&cOc4&0cOc-&=03ccccccccc% c18883c ccccccccccccccccccccccccccc />&cNc'cPc .6 .6 7 .7. 8cccccccccccccccccccccccccccccccccccccc % c188@3c cccccccccccccccccccccccccccccccccccccc c 6cccccccccccccccccccc:&cNcc#&cOc4&0cOc-&08c ccccccc ccccccccccccccccccccccccccc />&cNc'cPc .6 .6 7 .7. 8cccccccccccccccccccccccccccccccccccccc % c188<3c c 6ccccccccccccccc ccccc:&cNcc#&cOc4&0cOc-&=0c >" cc/ cD"c ?c c" ccc - c " c c c c c c c c 6c #&c 4&c c -&c c c c " c c c c D"c c c c c c c c c#&c c4&c cccc c!>0c c c ccc ccccc cc c c c c c c c c c " c c c c %c c c #&c 4&c c -&=!>0cc#c c ccccc cc cc" c c c c cc c c Cuando se selecciona el botón de radio de Cij/NRTL se está seleccionando la opción para especificar el parámetro Cij, a menos que se esté aplicando la regla de mezclado de Wong Sandler, para cuyo caso se estarían especificando los coeficientes binarios usados para determinar la energía Helmholtz. c Regla de Mezclado Wong Sandler c c c" cc/ ccD"c cc c" c ccc c c c c c c c c c c c c c c c c c c c c c c c c " c 6c c þc %ccc%" cc cc c þc c c c c c c c c " c c c c 2 c cccc cc c cc" cc ccc cc c cc c cc6c c c c c c % c188(3c c c 4103cNccc?c c ù c -c c c c c " c c c c c c c" 6c c 4& 103cc c c % c188*3c c c 4103cN c c4cc c c188(36c c cccc c c 4& 103c c c % c188I3c c?c cNc ù c c 2 c cc c c c c 188I3c c c c c c c c c" 6c c c c c cNcc 6 7 76 > ?@ 9 8 :; <= cc c c 6ccccccccc cNc713c c c c 6ccccc713cc c c c c c % c188J3&c c % c188H3c %c" cc c cc c c18J3cc c ccc ccc cc c" c 6c c c A 8 2c BC DE F F 86 8 ?@ ?@ c%# G H * c c c c c c c c c " c c c c c c c c " cccc c c cc&cc cc" c c c0cc2c c c c ?@ P G 1023c?cG IJ 1023cNcK L MNF c O L cc ù NF c c ccc # c c c cc & cc ccc c c c c c c c c c c & c c %c c c c c ccc ccc2c c c c cc 6c c c c c : Q F cNc c c : Q F7 cNc7 c c %c ccc cc cc c" c 6c c c c c c c c c Ncc c c c713c6ccc c O 6 7 76 9 8 :; <= c F RT S 7 UV ?@W ?@ cNc0 c?cG c 713cNcc Nc0 c?cG c c c" cccc G c c cc c!>0cc2 cc c c cc cc ccc cc c c c c cccc cc-&=!>0c c Parámetros de Interacción de Ecuaciones de Estado %c c c c c c c c c c c c " c c c c c c cc cc cc c c c c c c cc" ccc c ccc c c 6c c Figura 2.24 c c c c +c c c " c c c c c c c c c ccc c ccc c cccc c c c " c 1????3c c c c c c c c c c c c c c 2 c c c cc cc2>Ac:&cNc:&c c c cc cc c c " c c " c c c c c c c c c c c c c c c c 2 c " c c c c 2>Ac c cc:&c cc c c cc cc cc ccc cc cc c c c c c 2>c c >Dc 1c c " c c c c 3c c " c c cc cc c ccc c cc " cc%cc c c c " c 6c c 4cc> c 9c Estimate HC-HC/Set %c c c c c c cc cc c cc ccc c ccc cc Non HC-HC to . c c c & c c c c c c cccc - cc c c c c c c c Set all to . c c c c c c c c c c c c))cc c c Parámetros de Interacción de Modelos de Actividad - cc cccc cc2 cc7 c c c:cc c cc" cccc cBinary Coeffscc" c c c c cccc ccc cc c" c" 6c c Figura 2.25 c c c c c c c c c c c c c " c c Vc c c c c c c c c c " c c c c c c c c c c c " c c c c c c c cccc cccc c" cc c 2 c" cccc#&c4&cG&=-&ccc cccc c c c c Métodos de Estimación c - c c "c c c c c c c c c c c c c c c c c c c c c c c c c :c c c c c c c c c c c c "c c ccc" c6c c Botón Descripción c c c c c c c c UNIFAC VLE s!57#-cc% cA c cc c c c c c c c c UNIFAC LLE s!57#-cc% cA c c - c c c c cImmisciblec c c c Immiscible cc ccc" 6c þc Row in Clm Pair: c c c c cc c c c ccc c c 1&3c c c c c c c c c13 þc Clm in Row Pair6c c c c c c c c c ccc c c c13cccccc c c1&3 þc All in Row6cccs ccc c cc c c c c c c c -c c c c Dc c & c c c c c c c c c c c c " c c c UNIFAC LLEc Immisciblec cc cc2 cc7 c c c c c c s!57#-c c c c c 8(W-c c c c c cc c cc c" cSet Upccc c cc c"c c cccs!57#-cA%cccs!57#-c%c c c c c c c c c c c c c c c c c " c c ccc6c c 4c 9c %c c c c c c c c Individual Pair cccs!57#-cA%cc- cc c c #&c c #&c c c c c c c c c ccc c cc c c c c c c c c c c c c c Unkowns Only c c c c c c c c c c c cc cc cc cc cc cc cc cc %cc ccc ccc c All Binaries c c cccc c c " ccc c " cc c cc ccccc cc c c c 0 c c c c c c " c c :c c c cReset Paramsc c c 2.4.4 Pestaña de Página del Test de Estabilidad (Stab Test Tab) %ccc c cc cc c cc c" cc+c cc cc c" c "ccc c c ccc ccc c c 2 c c c c c +c c c s c c c c c c c " c c c+c c c c c c c ccc cc2c&cc c ccc c ccc c ccccc c ccc cc+c c c c c c cc%c c c c c " c c c c c c c c c c c c c c c c c c c c cc+cc cc c c %c c c c c c c c c c & c c c cc ccc " cc &ccc cc cc cc c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c " ccccc" 6c#ccc c c c c cc c cc c c c & c c c c c c cc c c ccc cc c c c Figura 2.26 c Recuadro de Opciones de Modo Flash Dinámico c c c c c c c c c c c c " c ccc6c c 7 c.c 9c % c c c c c c "c c Try IOFlash First cc5c. c cc c ccc c c c c & c c c c c " cc% c"c ccccc c c c c c c % c c c c & c c " c c c c c c "c 2 c c 0c c % c c c c c c c c c "c c c c " c c c c c & c c c c c c c c c c c c c c c c c c c c c c c c c c 2 c c c c c c c c c c c+c c c c c c c c c c c c c c c c c c none c ccc c c c c c c c c c cc c % cc cc c " c ccccc Flash3 %c c c c c & c c c c c c c " c c c c c c c c c c cccc ccc2c cccc c c" c c c ccc %c c c "c c c c c c c & c Multi Phase cc c c c c c c c c cc cc cccc ccc Use Multiple Phase % c cc ccc c cc cc cc "c cccc cccc cc Estimates c c c c c c c c " c c ccc c c c c c cc c5.7 c cc cc c c cc cc c c cc "cc c c c c c c c c IOFlashc c c c c c c c c &c 1Flow Presure Solver3cc c " cDynamicscc c Preferencescc c c cc c cc& cc c cc c cc c c c c % c c c c c c c " c c c cc" ccccc ccc cc cc cc cc5.c c c c c c c c c c c 1c c c c c c c cccc 3cc c cc c ccccc c c c c c c c c c c c 8<(cPhase Order Tabc c 2c c c c c c c c c c c c c c c c c c c c cc cc%ccccc c12 c.c/3cc c c c c c c c c c c c c c c c c c c cc c Recuadro de Parámetros del Test de Estabilidad c %c c c c c c cc c cc c c c c +cc cc18cc@3cc c cc"cMaximum Phases Allowedcc c cc& c c c cc c cc c c c c c ccc ccc cc. c cc c ccc c cc c c cc c ccc c cc c c c %c cc% c cc cc/cc%cc ccc c c cc cccc cc c ccc c & c c c c c c c c c c c c c c c c c" c" 6cccc c c c %c c" c cccc6c c Botón de Radio Descripción !cc& c"+ccc cc None s c c c c c c c c c c c Low ccc cc%cc c c c c c c c c c Dc c c c c ccc " ccccc #c c c c c c c c ,c c Medium c c c c c c c c " c c c c c c c c c c c c c ccc c 0c c cccc c c ccc All 2c c c cc c c c User c c c c c c 7 c c c c 0c c c c cc0ccC cccc c "+c c c c c c c "+c c c c c cccccc c cc c HYSIM Flash %c c c c c c c 5/c c c c c ccc c c c cc c c c 5/c c "+c c c c c c c & cc % c c c c c c c c c c 5/c c % c c c c c c c c ccscc c7#@c cc cc cc ccccc c!cccc c c Recuadro de Fases de Inicio del Testc c %c c c c c c c c c c c c 1Phases to Initiate Test3cc c cc cc c c ccccc ccc c ccccc cc cc c cc ccc c cccc ccc cccc ccUsercc%c c c " c c c c c c c c c c c c c cc6c c c c c Checkboxes Deleted c Descripción cc c c c cc ccc c c" cc c c cc c of c c c c c c c c c " Vc c" ccc cc c s c c cc" c cc c c c c cc cc ccEc cc c ccDc c cccc c Average Existing Ideal Gas Wilson´s equation c c s cc c cccc ccccc ccc cc c cccc " c c cc2c ccc&ccc c c c c c c c c c c c c c c 2c &c c c c c c !>0c c c c c c c c c c c c cc cc+cc cc c cccc c cc2c c c c c c c c c c c c c c c cc c c c c c " c c c c c c c c c c+c c c cc c c ccc cc ccc ccc+c c c c c c c c c c c c " c c c c c c c c c c c c c c c c c c Limites de Temperatura c c c c c c "c c c c cc c c & c c c c c c c c " c c c c c c c c c c cc cc c c cc ccc c c c c c " c c c c c c & c c c c ccc cc c ccc c cc c c" ccc cc cc c cc c c Componentes para el Inicio del Testc c - c c" cc+cc ccc c c" c ccc c c c c c c c c c c . c c c c c c cc c" cc cccc cc2c&ccc c c c cc " c c c c c" cc c c" cc cc c" cc " cc cc c" cccc cc c ccccccc1Comps to Initiate Test3c c c c c 2.4.5 Pestaña de Página del Orden de las Fases (Phase Order Tab) c c c c c c c c" c c c c c c cc %cccccc cc c ccc cc c c c c c c c %c c c c c c c c ccc c c cc c cccc c c c c cc%ccc c ccc c c c" c c c ccc c c c c c c" c c c c c c c cccc cc1 cc 3ccc cc ccc "c ccc c cc c c c cc c c c c c c c c c c c c " c c c c c c cc" cc cc cc2c&c c c c c c c c c & c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c %c c c c c c ccc cc cc c" c" 6c c c Figura 2.27 c c Utilización de Tipo de Fase y Densidad (Phase Type and Density) c % c c c c c c c ccc %c c cc c c c " c c c c c " c c &c c c "c c c c c c c c c c c c c c " c c &c1cc" c c" 3ccc c ccc c User. Esta opción también cambia el orden de fase en el modelo estático o estable. Aunque en el modelo dinámico muchos de los cálculos dependen del tipo de fase y no del orden, por tanto esto no debería tener ningún impacto significativo. Utilización de Componentes Primarios Especificados por el Usuario (User Specified Primary Components) c c c c c c c c c c " c c c c c c c c 12 c 2 c -3c c c c c c c c c c c c c c 'c c c c c c c c 8c c % c c c c c c c c c c c cc c cc cc cc cc c c c c c c c c " c c c c c c c c c c cc c c c c c c c c c c c c 'c c c c c 'c c 9c c c c c c c c c c c ccc c % ccc c 6c c þc c& c c c c" ccc c c c þc c cc cc c c c c þc s ccc cc ccc c c cc cc c c 2.4.6 Pestaña de Página de Reacciones (Reactions Tab) c c 9c c c c c c c c c c c cc c c c cc cc" cc cc4/c9cc c cc " c c c c c 2 c c 7 c c cc c c c & c c c & cc& "cc ccc c Figura 2.28 ccc c c c c c &c c c c c c c c c c c c c c 2 cc2 ccc c 6c c Objeto Descripción Current Reaction %cc c cccc& "cc c c " ccc cc c Sets c c c c c c c cc #c Associated c" c c c c ccc& "c Reactions c c cc %c c " c c & "c c c c c c c Add Set c c c c c c c " c c c c Current Reactions Setscc Remove %cc cc& "cc c cc c c c % c cc c" ccc cc& "cc Available ccc c Reactions Sets Simultaneous Basis c :c c c c c c c # c c > c Manager 2.4.7 Pestaña de Pagina Tabular (Tabular Tab)c c %c c c c c c"c c c c c c c c c c c cc " c c & c c c c c cc%c2 c0 cc cc c& cc ccccc c c cc2c c c &c c c c c cc cc c cc c cc cccccc c c cc cc ccc # c c c c c c c c c c c c c cccc cc cc&c c c & c c c c c c c sc &c c c c c c c c c c c c c c 2 c 0 c c &c c c c /cc# c c c c c2 c cc c c c c c c c cccc cc ccc c cc c c c c c c c c c c c c c c c c c c c c c c c " c " c c c c c c c %c c c c c c c c c "c c c %c c c c c ccccc c cc& c c "c c c c c c c c cc % c c cc+ccc c c c cc cc%c@8c cc c c@8c ccccc8Hc cccc$c c c c c c $c c c c %c c c c c c c c c c c c c c c c & c c c c c cc!ccc c c c c ccc"c c c ccsc c c c&ccc & c c ccc c c c !c c c c c c c c c c c c c c c ccccc c c c c c c " c c c c c c c c c c c c c c c c c cc cc cc#ccc c cc c c c c c ')))c c c c c c c c c c c c c c c c c c c " c c c ccccc c - cc c c cc cc c ccccc" ccc c c 2cc cc c c c c cc c cc cc229c c ccc c cc% c cc cc c c c ccc cc c c ccccc c cc c"c c c c c c cc- cc/ cc c cc ccc cc2 cc c c ccc cc cc cc cccc c cc cccc cc c& c cc cc c c c c c c c c c c c c c c c c c c c c c c c "c c c c c c c ccccc c c c c c c c c c c c c %9%c c %c c c c c c %9%c c c c c c c c c c" c cc cc c c"c c c c c Requerimientos para Uso del Paquete Tabular c c c c c c c c c2 c0 cc2c c c c c c c c c c " c c c c c c c 0 c c " c c c c c c c c c c c c c c c c c c c c c c c 2c &c c c ccc c c c c c cc ccs c ccc c c c cc c cc cc- cc c c c c c c c c c c c c c c c c Límites de La Opción Tabularc c %c c cc c ccc cc c c10 3ccc c c c c 103c c c c c c c c c c cc c c" c c" c c c cc%cc c cccc c c c c c c c c c c c c 9c c c c c c c c c " c c c c cc cc0 c c0ccccc c c c c cc c cc c c %ccc c cc 6c c þc 5 c c c c 0 cc c c " c c cc c "ccc c c c cc c cccc c c c c c c0c c c c ccc c c c c c c c cc c c c &c c c c þc s c c c c /c c % c c c 0c c % c c c c c c cc cccc c c cccc ccc cc2c cccc0c c c cc c c0c1c ccccc cc c cc c cccc3c cc)IIc c)HHc c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c c cc c c c c c c ccc c c c c c c c " c c c 229c 1c c c 2293c c c c c c c c c c c c c-c cc c c c" cc cc%c c c c c cc cc c cc cc c c c c cc c c c c ccccc c