Downloaded from http://sp.lyellcollection.org/ at Ludwig-Maximilians-Universität München on February 27, 2013 Geological Society, London, Special Publications The link between metamorphism, volcanism and geotectonic setting during the evolution of the Andes L. Aguirre, B. Levi and J. O. Nyström Geological Society, London, Special Publications 1989, v.43; p223-232. doi: 10.1144/GSL.SP.1989.043.01.15 Email alerting service click here to receive free e-mail alerts when new articles cite this article Permission request click here to seek permission to re-use all or part of this article Subscribe click here to subscribe to Geological Society, London, Special Publications or the Lyell Collection Notes © The Geological Society of London 2013 Downloaded from http://sp.lyellcollection.org/ at Ludwig-Maximilians-Universität München on February 27, 2013 The link between metamorphism, volcanism and geotectonic setting during the evolution of the Andes L. Aguirre, B. Levi & J. O. Nystr~im S U M MARY: A low-grade, non-deformational, regional metamorphism ranging from burial to ocean-floor type characterizes the Andean range. Longitudinal variations exist, coinciding with changes in the chemistry of the volcanic suites involved, both trends being controlled by the geotectonic setting. The study of Cretaceous volcanic rocks in Colombia, Peru and Chile indicates that: (i) ocean-floor metamorphism (high-T gradients) correlates with tholeiitic volcanism in marginal basins where the continental crust was eliminated or extremely attenuated; (ii) burial metamorphism (low- to moderate-T gradients) correlates with calc-alkaline to shoshonitic volcanism in ensialic, aborted, marginal basins with moderate thinning of the continental crust. The metamorphism in the Andes, which is characterized by a counter-clockwise P - T - t path, started during the initial stages of basin formation and preceded the orogenic activity, contrary to the development in compressional geotectonic settings. A relationship between the geochemistry of volcanic rocks and their tectonic setting has been demonstrated by numerous authors (e.g. Pearce 1983). A link between nondeformational low-grade metamorphism and geotectonics is implicit from the description of many volcanic terrains. An obvious relationship exists between ocean-floor metamorphism and the setting for ocean-floor lavas in Recent and fossil mid-ocean ridges (Spooner & Fyfe 1973, Elthon & Stern 1978, Cann 1979, Stern & Elthon 1979, Alt & Honnorez 1984, Alt et al, 1986). However, few investigations have been concerned with the variation of regional nondeformational metamorphism in other settings. Aberg et al. (1984) and Aguirre & Offler (1985) suggested that the type of metamorphism, ocean-floor (steep thermal gradient at an oceanic spreading centre) versus burial (low to moderate thermal gradient, essentially related to load pressure and independent of younger intrusions, in a continental setting), was related to basin type (marginal basin proper versus aborted, ensialic marginal basin) during the Cretaceous evolution of the Andes. Here, we give evidence for this suggestion, showing that metamorphic patterns, palaeothermal gradients and volcanic chemistry are directly linked to geotectonic evolution. The commonly used three-fold division of the Andean Cordillera into the Northern, Central and Patagonian Andes (Fig. 1) reflects essential crustal differences. The continental crust, thin and with exposure of oceanic crust in the Northern and Patagonian Andes, attains a thickness of 70 km in the Central Andes. The boundaries between the three segments are major geotectonic breaks: the GuayaquilRomeral Megashear system separates the Northern and Central Andes, and the Chile Rise (Nazca-Antarctica plate boundary) marks the dividing line for the Central and Patagonian Andes. The evidence for a link between nondeformational low-grade metamorphism and geotectonic setting emerges from a comparison of four Cretaceous volcanic sequences: (i) the Diabase Group in Colombia; (ii) the Casma Group in Peru; (iii) the Ocoite Group in central Chile; and (iv) the Rocas Verdes Group in southernmost Chile (Fig. 1). These units are the best documented cases of low-grade metamorphism from different Andean tectonic settings. The Diabase Group (Northern Andes) The Western Cordillera of Colombia is largely made up of fault-bounded blocks of basaltic lavas (some pillowed), intrusions and minor sedimentary intercalations, generally referred to as the Diabase Group. The age of the Group is probably Barremian-Turonian (Barrero 1979). The intrusions comprise numerous dolerite dykes, and some gabbroic and ultrabasic bodies. The total thickness of the Group probably exceeds 5000 m. However, since thrusting is the dominating tectonic style (Bourgois et al. 1982, Marriner & Millward 1984), the original thickness could have been considerably less. The basalts are low-K tholeiites with geochemical characteristics From DALY,J. S., CLIFF,R. A. & YARDLEY,B. W. D. (eds) 1989, Evolution of Metamorphic Belts, Geological Society Special Publication No. 43, pp. 223-232. 223 224 Downloaded from http://sp.lyellcollection.org/ at Ludwig-Maximilians-Universität München on February 27, 2013 L. Aguirre et al. b Peru ", i "" i I Bohwa 1,... ..... ,:-- Chile..; iI ¢~ s ,'t ; g " i i Ocoife ', Group Diobase Group J i i Argen- (a) laumontite _+ (heulandite) + quartz + chlorite + albite (b) laumontite + pumpellyite + chlorite + quartz + albite (c) laumontite + pumpellyite + prehnite + chlorite + quartz + albite tina , ,,., f tt"" whereas in the prehnite-pumpellyite facies the following calcite-free association occurs in amygdules: Peru (d) prehnite + pumpellyite + quartz + chlorite + albite -Io" CnsrnQ ~I I epidote + No assemblages diagnostic of the greenschist facies were reported. Group I among others). Martinet & Millward (1984) and Millward et al. (1984) favour an oceanic flood-basalt origin for the Group due to similarities with basalts from the West Pacific Nauru Basin. An alternative setting of the Diabase Group, according to these authors, is a marginal basin resembling the Gulf of California. The rocks of the Diabase Group are affected by low-grade regional metamorphism in zeolite, prehnite-pumpellyite and greenschist facies (Barrero 1979, Espinosa-Baquero 1980, Rodriguez 1981). The secondary changes have been ascribed to ocean-floor metamorphism by Espinosa-Baquero (1980), based on the spilitization pattern and primary chemistry of the rocks. Bastouil (1985) found that in the B u g a Buenaventura section (4°N; 54 samples studied) the zeolite facies is represented by the following calcite-free associations in amygdules: Group ~ I Marginal bosins, proper Marginal bosins, oborted {heavy hatching in tronsitionol zones) Oceanic island orc FIG. 1. Distribution of volcanic rocks in Cretaceous marginal basins along the western part of the Andes. The Northern Andes extends from Colombia to the Guayaquil-Romeral fault system (GR-MS); the Central Andes is from GR-MS to the Chile Rise (CHR); the Patagonian Andes lies to the south of the Chile Rise. Modified from Aguirre (1987). approaching those of T-MORB (Barrero 1979, Millward et al. 1984, Bastouil 1985). The Diabase Group is regarded as an accreted ophiolitic complex by many authors (Barrero 1979, Espinosa-Baquero 1980, Bourgois et al. 1982, McCourt et al. 1984, Based on the composition of the metamorphic minerals Bastouil (1985) concluded that: (i) prehnite, pumpellyite and epidote are Ferich, indicating a high oxygen fugacity; (ii) the Fe content is higher in the pumpellyite than in coexisting epidote; (iii) the X~e values decrease from pumpellyite through epidote to prehnite contrary to the trend in most terrains of lowgrade metamorphism, where epidote has the highest XFe. The passage from zeolite to prehnitepumpellyite facies is illustrated in a schematic pseudobinary T - - X F e diagram (Fig. 2) using the compositions of prehnite, pumpellyite and epidote present in assemblages (a) to (d). With increasing metamorphic grade the XFe-COntent of epidotes decreases from zeolite facies to the transition to prehnite-pumpellyite facies, then slightly increases in the latter. The facies transition in the Diabase Group appears to be defined by the reaction: laumontite + pumpellyite + quartz = prehnite + epidote + chlorite + H20 Downloaded from http://sp.lyellcollection.org/ at Ludwig-Maximilians-Universität München on February 27, 2013 Andean metamorphism, volcanism and geotectonic setting PP 144 139 T 225 / II 134 ZEO 110 109 I 0 ~0 \ I ~ l / l [ 20 30 I I z,o 50 60 100 X Fe3,, FXG.2. Schematic pseudobinary T - X F e diagram (after Cho et al. 1986) based on the compositions of prehnite (open bars), pumpellyite (hatched bars) and epidote (filled bars) in calcite-free amygdule assemblages, Diabase Group, Colombia. One hundred and fifteen microprobe analyses in five polished sections. The samples (numbers at left) have been placed qualitatively on the T axis in order of increasing metamorphic grade, but the separation between successive samples is arbitrary. Curves = mean values of Xw in each mineral; horizontal line = zeolite-/prehnite-pumpellyite-faciesboundary. The diagram suggests the following approximate XFe values for the phases in this reaction: prehnite (0.09), pumpellyite (0.34) and epidote (0.29). They permit an estimation of the P - T values for the transition from zeolite to prehnite-pumpellyite facies, using the petrogenetic grid of Liou et al. (1985): T = 165 + 5°C and P --- 1.05 + 0.05 kbar. Bastouil (1985) points out that a steep T gradient typical of ocean-floor metamorphic conditions can be inferred from the mineral chemistry of the phases in the prehnitepumpellyite facies assemblages. For example, the pumpellyites plot in an Fe-rich area of the A I - F e - M g diagram close to the field of pumpellyites reported by Liou (1979) from the Taiwan Ophiolite, which is affected by oceanfloor metamorphism. The proportion of Si is slightly higher than the ideal 6 atoms per formula unit, and there is a simultaneous saturation of the X and W sites. These features point to metamorphism of a low-pressure type with participation of fluids enriched in Si, Ca and Fe. Finally, high oxygen fugacity (indicated by the Fe-rich pumpellyite) and low pressure are consistent with metamorphism taking place under a shallow water column, a condition compatible with a marginal basin environment. The Casma Group (Central Andes) An approximately 3000-m-thick marine volcanic sequence of Albian age known as the Casma Group crops out along the coast of Peru (Fig. 1). The sequence , constituted by several litho- logical units separated by regional unconformities, occurs as elongated blocks delimited by faults (Cobbing 1985, and references therein). Casma rocks from two areas are treated in this paper: one situated between 10° and 12°30'S (here referred to as the Northern Casma) and another at c. 14°S (the Southern Casma). The Casma Group consists of pillow lavas, tufts, hyaloclastites and subordinate amounts of non-volcanogenic sedimentary rocks deposited in a basin. The Northern Casma lavas are predominantly basalts and range from low-K tholeiites to calc-alkaline compositions. The lavas from the Southern Casma sequence are basaltic andesites and andesites of calc-alkaline to high-K calc-alkaline affinity (Atherton & Aguirre, in preparation). The Casma volcanics are closely associated in the field with coeval intrusions of gabbro and a large number of dolerite dykes (suggestive of a sheeted dyke complex); ultrabasic rocks have not been reported. Due to mineralogical and geochemical similarities, a genetic link between the extrusive and intrusive rocks is likely (Atherton et al. 1985, and references therein). Gravity profiles have revealed the existence of dense material (3.0 g cm -3) with a seismic velocity of 6.66 km s -1 at a high crustal level along the axis of the Casma basin (Jones 1981, Couch et al. 1981). The profiles show that the continental crust below the Casma basin becomes thinner towards the north, suggesting that upwelling of mantle material to shallow levels took place here. The depositional environment of the Casma volcanics was controlled by deep-reaching faults during an 226 Downloaded from http://sp.lyellcollection.org/ at Ludwig-Maximilians-Universität München on February 27, 2013 L. Aguirre et al. extensional regime (Cobbing 1985) which resuited in an extreme crustal thinning. The 'quasi-ophiolitic' nature of the Casma Group in its northern exposures, together with the regional structure and geophysical data, point to a marginal basin as the most probable tectonic setting of the Group. However, the extension did not result in the creation of oceanic crust, as shown by the lack of a proper ophiolitic complex and the relatively evolved chemical character of many of the lavas. Thus, the Casma basin should be considered as an aborted marginal basin of ensialic character since it is situated in continental crust (Atherton et al. 1985). According to Atherton et al. (1983, 1985) the Casma volcanics are geochemically similar to lavas from some ensialic back-arc basins erupted during the splitting of a calc-alkaline volcanic arc (e.g. the basalts from the Sarmiento complex, the Bransfield Strait, the inner part of the Gulf of California, and the Scotia Sea). The Northern Casma volcanics show a complex pattern of low-grade non-deformational metamorphism, covering the zeolite, prehnitepumpellyite and greenschist facies. Several facies series comprising the whole or part of this range are displayed in lithological units separated by regional unconformities. The structural breaks coincide with breaks in secondary mineralogy, where strata of higher grade overlie strata of lower grade. This pattern has been attributed to an episodic history of burial metamorphism (Aguirre et al. 1978, Offler et al. 1980, Aguirre & Offler 1985). Rapid changes in facies with stratigraphic depth within the different facies series of the Northern Casma sequence demonstrate that thermal gradients were high to very high. For example, there is a range from zeolite to greenschist facies in one unit c. 360 m thick,i m p lying a gradient of more than 300°C km -a_ The presence of wairakite (Offler et al. 1980) and the absence of pumpellyite-actinolite assemblages and lawsonite confirm the leading role of temperature during this metamorphism. Moreover, the chemical features of actinolites in greenschist facies assemblages are consistent with low pressure and a high thermal gradient (Offler & Aguirre 1984). Secondary assemblages of higher temperature have been recorded in the vicinity of volcanic centres (Cardozo & Wauschkuhn 1984), and the thickness of the volcanic sequence and the ratio of volcanic to sedimentary rocks decreases with lateral distance away from the centres. Hydrothermal metamorphism transitional between burial and ocean-floor type is in better agreement with these patterns than the previous interpretation (burial metamorphism). In the Southern Casma sequence the thermal gradients were less steep, as shown by a monotonous display of epidote-poor prehnite-pumpellyite facies assemblages (Aguirre & Offler 1985, Atherton & Aguirre, in preparation). The Ocoite Group (Central Andes) The 3-13-km-thick Ocoite Group, of Berriasian to Albian age, constitutes a c. 1000-kmlong belt of volcanic rocks in the Coast Range of central Chile (Fig. 1). It is part of a synclinorium which exhibits an overall symmetry with regard to structure, stratigraphy and pattern of cross-cutting dykes (Aberg et al. 1984). The following description refers to the section between 32030' and 33°30'S (latitude of Santiago). The lower third of the 9-km-thick sequence consists mainly of marine and continental volcanic sediments, limestones, dacitic ignimbrites and interbedded basalts. The main (central) part of the lava pile is made up of continental basalts and basaltic andesites morphologically similar to flood lavas, with conspicuous phenocrysts of plagioclase. In this paper we use the local name for this characteristic rock type ('ocoite') as the name for the entire Group. The uppermost part of the sequence consists of continental flow-breccias of basaltic andesite to andesite composition. Most of the basic lavas belong to the high-K calc-alkaline and shoshonite series (Levi et al. 1987). In the northernmost part of the belt the Group is less thick, ignimbrites are absent or scarce, and the depositional environment was predominantly marine. Here, the basic lavas are calc-alkaline, though poorer in potassium than in the south. The lavas of the Ocoite Group were erupted in an extensional ensialic setting, characterized as an aborted marginal basin by Aberg et al. (1984). The huge thickness of the volcanic pile together with a low geothermal gradient suggest that the Group was deposited during the opening (spreading) of a rapidly subsiding basin (see below). Oceanic crust was never formed. The high potassium contents of the basic lavas imply substantial contamination by continental crust (Levi et al. 1987). The Ocoite Group ranges in metamorphic grade from zeolite facies at the top to greenschist facies at the very bottom of the pile (Levi et al. 1982, Aberg et al. 1984). This implies a moderate geothermal gradient of around 20-30°C km -~. No breaks have been observed in the facies series, suggesting that the burial Downloaded from http://sp.lyellcollection.org/ at Ludwig-Maximilians-Universität München on February 27, 2013 Andean metamorphism, volcanism and geotectonic setting metamorphism giving rise to it took place as a single, continuous episode. However, the uncomformities that define the top and bottom of the Group coincide with breaks in secondary mineralogy (Levi 1969) of the same type as described above for the Casma Group. The metamorphic pattern is quite persistent along the belt through outcrop distances of hundreds of kilometres. The metamorphism is nondeformational; primary structures and textures are preserved. Its grade increases with stratigraphic depth, regional facies boundaries being parallel or subparallel to bedding and not to contacts with younger granitoids, demonstrating that the metamorphism is unrelated to the intrusions. These characteristics conform to the definition of burial metamorphism (Coombs 1961). Calcite-free amygdules in rocks of the zeolite facies at the top of the pile are characterized by the assemblage: laumontite + chlorite + pumpellyite + prehnite + epidote In the prehnite-pumpellyite facies, characteristic associations include: the pumpellyite + epidote + chlorite + prehnite The appearance of actinolite in the absence of pumpellyite and prehnite indicates the passage to greenschist facies at the bottom of the pile. The pumpellyite and epidote in the zeoliteto prehnite-pumpellyite-facies assemblages increase in XFe with increasing metamorphic grade (= depth; Fig.3) as already pointed out by Levi et al. (1982). In epidote coexisting with pumpellyite in amygdules, F e 3+ is preferentially concentrated in the epidote. The transition from the zeolite to the prehnite-pumpellyite facies would be defined by the reaction: laumontite + pumpellyite + quartz = prehnite + epidote + chlorite + H20 with approximate XFe values of 0.12 for the pumpellyite and 0.24 for the epidote. Using the petrogenetic grid of Liou et al. (1985) the following approximate P - T values are obtained for the transition from zeolite to prehnitepumpellyite facies: T = 175 + 5°C and P = 1.06 + 0.05 kbar. Geochronological data (Fig. 4) indicate that the burial metamorphism took place relatively soon after the volcanic rocks were extruded, pointing to rapid subsidence. The prevalence of metastable mineral assemblages and the fact that greenschist facies conditions were attained only at a stratigraphic depth of several kilometres indicate that the subsiding volcanic rocks 227 did not experience conditions of high temperature or pressure. This suggests lateral displacement away from the axial thermal high of the subsiding basin (Levi et al. 1982). The Rocas Verdes Group (Patagonian Andes) The Rocas Verdes Group is a c. 600-kmlong belt composed of basic igneous rocks of Late Jurassic to 'Middle' Cretaceous age in the southernmost Patagonian Andes (Fig. 1). It is up to 3500 m thick and has been interpreted as an ophiolite complex that formed in a marginal basin (Dalziel et al. 1974, Stern 1980, Dalziel 1981, and references therein). The lavas and dykes of the Group are tholeiites, displaying affinities with ocean-ridge basalts rather than with island-arc tholeiites. Calc-alkaline volcanism took place contemporaneously in a volcanic arc located west of the basin (Su~irez 1979). According to Elthon & Stern (1978) and Stern & Elthon (1979) the c. 2-km-thick upper part of the Rocas Verdes Group is metamorphosed in zeolite to 'upper actinolite' facies (the latter corresponding to amphibolite facies according to the mineral assemblages given by these authors; amphibole with 5.0-8.0 wt % A1203, calcic plagioclase and titanomagnetite). This metamorphic pattern implies a steep thermal gradient (probably about 180°C km -l) and has been interpreted as the result of hydrothermal ocean-floor metamorphism at a spreading centre (Elthon & Stern 1978, Stern & Elthon 1979). The metamorphic facies have a rather heterogeneous distribution and are typified by the abundant presence of 'retrograde' disequilibrium textures, which are the result of a sequential series of metamorphic reactions occurring with decreasing temperature. In spite of the heterogeneous facies distribution there is a clear tendency of increasing grade downwards in a short vertical distance, from zeolite to amphibolite facies (Stern & Elthon 1979). Concluding remarks The four case studies show that rifting occurred during the Cretaceous and marginal basins, 'proper' or aborted, were generated along the western border of South America. Crustal thinning took place with varying intensity at different latitudes; moderate in central Chile 228 Downloaded from http://sp.lyellcollection.org/ at Ludwig-Maximilians-Universität München on February 27, 2013 L. Aguirre et al. PP 669 II /-.48 333 327 329 288 177 ZEO 282 I I I 10 20 30 4.0 XFo3. 100 FI6.3. Schematic pseudobinary T--XFe diagram (after Cho et al. 1986) based on the compositions of pumpellyite (hatched bars) and epidote (filled bars) in amygdule assemblages, Ocoite Group, central Chile. Forty-seven microprobe analyses in eight polished sections. The samples (numbers at left) have been placed qualitatively on the T axis in order of stratigraphic depth (= metamorphic grade), but the separation between successive samples is arbitrary. Curves and horizontal line as in Fig. 2. I l I I I I ! I ,'<b 13 &. t_9 £1_ ..Q Cl I 0 I I I 100 I 200 I 300 I I 400 Temp. °C FIG. 4. Schematic P - T - t history for the Ocoite Group, central Chile. Orogenic phase 1 can be correlated with the Oregonian (mid-Cretaceous) orogeny around 100 Ma (Aguirre et al. 1974). Ages (in Ma) are based on palaeontological evidence for point a (extrusion of the basaltic flows), and Rb-Sr whole-rock data for point b corresponding to the age of the prehnite-pumpellyite-facies metamorphism of the flows (Aberg et a11984). Reaction curves based on Liou et al. (1985) modified to take account of the actual epidote compositions. (Ocoite Group) to extreme in Peru (Northern Casma Group). The crustal attenuation resulted in rupture at both ends of the continent (Diabase Group to the north and Rocas Verdes Group to the south). We envisage that marginal basin formation was controlled by subduction of an oceanic plate alternating with crustal spreading in the overlying continental margin (Fig. 5), as proposed by Aberg et al. (1984) for central Chile. A cyclic repetition of this process Downloaded from http://sp.lyellcollection.org/ at Ludwig-Maximilians-Universität München on February 27, 2013 Andean metamorphism, volcanism and geotectonic setting A B 229 J _-_ ::v~i:if FIr. 5. Marginal basin generation in the Andes during the Cretaceous. A--rapid oceanic spreading and 'Chile type' plate convergence (low-angle subduction; Uyeda & Kanamori 1979). Generation of a convective cell below the continental margin. B---establishment of an extensional regime in the continental margin (doming, rifting) and diapiric rise of mantle material (the intensity of the shading reflects the temperature). Melting of the continental crust leads to bimodal volcanism (ignimbrites and subordinate basalts). C--increasing rate of intra-continental spreading, and blockage of the downgoing oceanic slab at a steepening angle ('Mariana type' convergence; Uyeda & Kanamori 1979), resulting in (1) a marginal basin proper (rupture of the continental crust and formation of an ophiolite suite), or (2) an aborted marginal basin (thinning of the crust and generation of flood basalts; this case is illustrated in the figure). Spreading-subsidence, heat dissipation and metamorphism (of ocean-floor and burial type, respectively). The convective cell comes to a halt. D--decoupling of the oceanic plate results in a short period of compression in the continental margin, manifested as an orogenic phase (see Mrgard 1978). Emplacement of batholith granitoids (not shown) takes place at the end of this phase. An increasing rate of oceanic spreading inaugurates a new cycle. could account for the geological evolution of the western margin of South America during the Mesozoic and Palaeogene. Upwelling rate and volume of mantle-derived material, thickness of the continental crust, rate of opening and other factors controlled the generation of the marginal basins (Aberg et al, 1984, Aguirre & Offler 1985, Aguirre 1987). They also determined the nature of the volcanism and the different metamorphic patterns and thermal gradients illustrated in the four case studies. The evolution of non-deformational metamorphism under an extensional regime in the Andean marginal basins is well exemplified by the P - T - t history of the Ocoite Group (Fig. 4). The various stages of basin generation outlined in Fig. 5 are reflected in the shape of the P - T - t path. A high rate of intra-continental spreading (Fig. 5, stages B and C) corresponds to an increase in T and P (a to b in Fig. 4) due to the diapiric rise of mantle material, intense volcanic activity and rapid burial. A second segment of the P - T - t path (from b to 1 in Fig. 4) rep- resents the terminal part of stage C (Fig. 5) when extension in the continent comes to a halt and heat dissipation is high. Decoupling and compression during stage D (Fig. 5) is represented by the orogenic phase 1. Finally, a third segment starting from 1, marks the uplift and cooling of the Ocoite Group. The geotectonic model envisaged here leads to a P - T - t path which emphasizes the special nature of the Andean metamorphism. Here, metamorphism starts during the initial stage of basin formation and precedes the orogenic activity, contrary to the development in compressional geotectonic settings. The resulting counter-clockwise P - T - t path was suggested by Robinson (1987) to characterize extensional settings. Some peculiar features of Andean metamorphism, such as its episodic nature, coincidence between mineralogical and structural unconformities, and prevalence of metastable metamorphic assemblages, can be explained by the mechanisms for basin formation outlined above. The rate of opening determines the residence time of the volcanic rocks in the hot axial region 230 Downloaded from http://sp.lyellcollection.org/ at Ludwig-Maximilians-Universität München on February 27, 2013 L. Aguirre et al. TABLE 1. Relationship between upwelling rate of mantle-derived material and the volcanic, metamorphic and geotectonic features of Cretaceous Andean marginal basins (modified from Aguirre & Offier 1985) Rapid mantle upwelling Moderately rapid mantle upwelling Slow mantle upwelling Marginal basin proper. Rupture of the continental crust with generation of oceanic crust. No contamination from continental crust Aborted marginal basin. Pronounced to extreme thinning of the continental crust. Slight crustal contamination Aborted marginal basin. Moderate thinning of the continental crust. Considerable crustal contamination Slightly evolved basalts and basaltic andesites of the calc-alkaline to tholeiitic series Evolved andesitic belts and basalts of the high-K calcalkaline and shoshonitic series Burial metamorphism transitional to ocean-floor metamorphism (very high thermal gradient) Burial metamorphism (moderate to low thermal gradient) Primitive basalts (ocean-floor tholeiites) in ophiolite suites Ocean-floor metamorphism (high thermal gradient) Examples: (1) the Colombian Diabase Group: (2) The 'Rocas Verdes' Group of Patagonia Example: The Casma Group of north-central Peru of the basin, and influences the nature of the metamorphic assemblages (maximum temperature recorded and extent of metastability). The lateral displacement (opening) will have the consequence that volcanic sequences deposited and metamorphosed during different cycles of the geological history will overlap each other. The metamorphic patterns in older volcanic sequences, separated by regional unconformities, will be preserved during subsequent episodes of burial metamorphism. This is due to their position away from the axial region, and because their low permeability, caused by infilling by secondary minerals, in effect seals them from Circulating fluids. The fact that the thermal gradients estimated for the Northern Casma Group (an ensialic aborted basin with extremely attenuated continental crust) are considerably higher than those inferred for the Diabase Group and the Rocas Verdes Group ('proper' marginal basins) can be explained by the more rapid heat dissipation due to larger volumes of fluids circulating through the rocks of the latter basins. Example: The Ocoite Group of central Chile. The upwelling rate of mantle material can be chosen as a parameter for comparisons of the volcanic, metamorphic and geotectonic features of the Cretaceous Andean terrains discussed above (Table 1). With regard to metamorphism, such comparisons allow the conclusion that: (1) ocean-floor metamorphism (including types transitional to high-T gradient, burial metamorphism) correlates with tholeiitic volcanism in marginal basins where the continental crust was eliminated or extremely attenuated; (2) burial metamorphism with low- to moderate-T gradients correlates with calc-alkaline to shoshonitic volcanism in ensialic, aborted, marginal basins with slight thinning of the continental crust. ACKNOWLEDGEMENTS: We thank J. S. Daly, F. Henriquez (University of Santiago, Chile) and an anonymous referee for constructive criticism of the manuscript. 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